Includes bibliographical references and index.
|Statement||edited by Alaa S. Abd-El-Aziz ... [et al.].|
|Series||Macromolecules containing metal and metal-like elements -- v. 8|
|Contributions||Abd-El-Aziz, Alaa S.|
|The Physical Object|
|Pagination||xiv, 206 p. :|
|Number of Pages||206|
ISBN: OCLC Number: Description: xiv, pages: illustrations ; 25 cm. Contents: The state of the art in boron polymer chemistry / Manoj K. Kolel-Veetil and Teddy M. Keller --Polymers incorporating icosahedral closo-dicarbaborane units / Mogon Patel and Anthony C. Swain --Boron- and nitrogen-containing polymers for advanced materials / Philippe Miele . Specifically, combination of the unique characteristics of boron-containing functional groups with the nano-size regime of dendritic structures and the self-assembly of polymers of well-defined architectures, such as telechelic polymers and block copolymers, allows scientists to develop next generation materials for sensing, electronic devices, catalysis, biomedical applications, by: As boron-containing polymers with ever more sophisticated chemical and electronic structures become available, people foresee a bright future with even more widespread use in materials science. A novel boron-containing carbon precursor with high yield and crystallisation (i.e., boron-containing arylacetylene polymers (PBAs)) was synthesised by the polycondensation reaction between arylethynyl Grignard reagent and boron trichloride-pyridine complexes. The precursor structures, curing behaviour and carbonisation were by: 3.
Of these, boron-containing conjugated porous polymers, featuring tunable geometric structures, unique Lewis acid boron centers and very rich physical properties, such as high specific surface, chargeable scaffold, strong photoluminescence and intramolecular charge transfer, have emerged as one of the most promising functional materials for optoelectronics, catalysis and sensing, by: 9. The functional polymer PS-Si was quantitatively borylated using BBr 3 to give poly(4-dibromoborylstyrene) (PS-B), a novel soluble boron-containing polymeric Lewis acid. PS - B readily reacted with nucleophiles serving as a precursor to a family of new polymers with boron centers of variable Lewis by: Boron-containing polymers have shown unique physicochemical properties which can be of great potential benefit in many fields. Although there have been several studies addressing different aspects of this class of polymers, there is still room for characteristic improvement for emerging by: 1. Abstract. During the s much research effort was devoted to boron hydride chemistry in a search for high-energy liquid fuels. This led to the discovery of polyhedral organoborane compounds, which were designated : J. P. Critchley, G. J. Knight, W. W. Wright.
The State of the Art in Boron Polymer Chemistry Manoj K. Kolel-Veetil and Teddy M. Keller Advanced Materials Section, Materials Chemistry Branch, Chemistry Division, Naval Research Laboratory, Washington, DC CONTENTS I. INTRODUCTION 2 A. A Brief Historical Perspective on Boron and Its Polymers 2 II. RECENT ADVANCES IN BORON-CONTAINING. Genre/Form: Electronic books: Additional Physical Format: Print version: Boron-containing polymers. Hoboken, NJ: Wiley-Interscience, © (OCoLC) This series provides a useful, applications-oriented forum for the next generation of macromolecules and materials. Applications include non-linear optical materials, specialty magnetic materials, liquid crystals, anticancer and antiviral drugs, treatment of arthritis, antibacterial drugs, antifouling materials, treatment of certain vitamin deficiencies, electrical conductors and. This paper introduces N -methyliminodiacetic acid (MIDA) as a unique protecting group for the boronic acid to stabilize boron-containing polymers. The synthesized MIDA boronate stabilized polymers show remarkable stability to the air, moisture, and chromatography.